Literature DB >> 29792688

Rhodium Complexes Bearing PAlP Pincer Ligands.

Naofumi Hara1, Teruhiko Saito1, Kazuhiko Semba1, Nishamol Kuriakose2, Hong Zheng2, Shigeyoshi Sakaki2, Yoshiaki Nakao1.   

Abstract

We report rhodium complexes bearing PAlP pincer ligands with an X-type aluminyl moiety. IR spectroscopy and single-crystal X-ray diffraction analysis of a carbonyl complex exhibit the considerable σ-donating ability of the aluminyl ligand, whose Lewis acidity is confirmed through coordination of pyridine to the aluminum center. The X-type PAlP-Rh complexes catalyze C2-selective monoalkylation of pyridine with alkenes.

Entities:  

Year:  2018        PMID： 29792688     DOI： 10.1021/jacs.8b04199

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  H2 and carbon-heteroatom bond activation mediated by polarized heterobimetallic complexes.

Authors:  R Malcolm Charles; Timothy P Brewster
Journal:  Coord Chem Rev       Date:  2021-02-07       Impact factor: 22.315

2.  Diverse reactivity of an iron-aluminium complex with substituted pyridines.

Authors:  Nikolaus Gorgas; Andrew J P White; Mark R Crimmin
Journal:  Chem Commun (Camb)       Date:  2022-09-27       Impact factor: 6.065

3.  Cooperative Activation of CO2 and Epoxide by a Heterobinuclear Al-Fe Complex via Radical Pair Mechanisms.

Authors:  Soumen Sinhababu; Maxim R Radzhabov; Joshua Telser; Neal P Mankad
Journal:  J Am Chem Soc       Date:  2022-02-14       Impact factor: 16.383

4.  Cooperative C-H activation of pyridine by PBP complexes of Rh and Ir can lead to bridging 2-pyridyls with different connectivity to the B-M unit.

Authors:  Yihan Cao; Wei-Chun Shih; Nattamai Bhuvanesh; Jia Zhou; Oleg V Ozerov
Journal:  Chem Sci       Date:  2021-10-05       Impact factor: 9.969

5.  Cooperative C-H Bond Activation by a Low-Spin d6 Iron-Aluminum Complex.

Authors:  Nikolaus Gorgas; Andrew J P White; Mark R Crimmin
Journal:  J Am Chem Soc       Date:  2022-05-05       Impact factor: 16.383

Review 6.  Catalysis using transition metal complexes featuring main group metal and metalloid compounds as supporting ligands.

Authors:  Jun Takaya
Journal:  Chem Sci       Date:  2020-09-10       Impact factor: 9.825
  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.