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Literature DB >> 29790561

Polymorphism of Ag₂₉(BDT)₁₂(TPP)₄^3- cluster: interactions of secondary ligands and their effect on solid state luminescence.

Abhijit Nag¹, Papri Chakraborty, Mohammad Bodiuzzaman, Tripti Ahuja, Sudhadevi Antharjanam, Thalappil Pradeep.

Abstract

We present the first example of polymorphism (cubic & trigonal) in single crystals of an atomically precise monolayer protected cluster, Ag29(BDT)12(TPP)43-. We demonstrate that C-Hπ interactions of the secondary ligands (TPP) are dominant in a cubic lattice compared to a trigonal lattice, resulting in a greater rigidity of the structure, which in turn, results in a higher luminescence efficiency in it.

Entities: Chemical Disease

Year: 2018 PMID： 29790561 DOI： 10.1039/c8nr02629g

Source DB: PubMed Journal: Nanoscale ISSN： 2040-3364 Impact factor: 7.790

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Cited

4 in total

1. Spontaneous Resolution of Chiral Multi-Thiolate-Protected Ag₃₀ Nanoclusters.

Authors: Jia-Hong Huang; Zhao-Yang Wang; Shuang-Quan Zang; Thomas C W Mak
Journal: ACS Cent Sci Date: 2020-09-29 Impact factor: 14.553

2. Enantioseparation and chiral induction in Ag₂₉ nanoclusters with intrinsic chirality.

Authors: Hiroto Yoshida; Masahiro Ehara; U Deva Priyakumar; Tsuyoshi Kawai; Takuya Nakashima
Journal: Chem Sci Date: 2020-01-20 Impact factor: 9.825

3. Polymorphism of Au₁₁(PR₃)₇Cl₃ clusters: understanding C-H⋯π interaction and C-H⋯Cl-C van der Waals interaction on cluster assembly by surface modification.

Authors: Chenwanli Qin; Qianqin Yuan; Peng Li; Shuxin Wang; Shuang Chen; Manzhou Zhu
Journal: RSC Adv Date: 2020-03-20 Impact factor: 3.361

4. Higher-order assembly of BSA gold nanoclusters using supramolecular host-guest chemistry: a 40% absolute fluorescence quantum yield.

Authors: Anjan Maity; Atul Kumar
Journal: Nanoscale Adv Date: 2022-06-01

4 in total

Polymorphism of Ag29(BDT)12(TPP)43- cluster: interactions of secondary ligands and their effect on solid state luminescence.

1. Spontaneous Resolution of Chiral Multi-Thiolate-Protected Ag30 Nanoclusters.

2. Enantioseparation and chiral induction in Ag29 nanoclusters with intrinsic chirality.

3. Polymorphism of Au11(PR3)7Cl3 clusters: understanding C-H⋯π interaction and C-H⋯Cl-C van der Waals interaction on cluster assembly by surface modification.

4. Higher-order assembly of BSA gold nanoclusters using supramolecular host-guest chemistry: a 40% absolute fluorescence quantum yield.

Polymorphism of Ag₂₉(BDT)₁₂(TPP)₄^3- cluster: interactions of secondary ligands and their effect on solid state luminescence.

1. Spontaneous Resolution of Chiral Multi-Thiolate-Protected Ag₃₀ Nanoclusters.

2. Enantioseparation and chiral induction in Ag₂₉ nanoclusters with intrinsic chirality.

3. Polymorphism of Au₁₁(PR₃)₇Cl₃ clusters: understanding C-H⋯π interaction and C-H⋯Cl-C van der Waals interaction on cluster assembly by surface modification.