Literature DB >> 29774331

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand.

Masaichi Saito1, Naoki Matsunaga, Jumpei Hamada, Shunsuke Furukawa, Mao Minoura, Susann Wegner, Juri Barthel, Christoph Janiak.   

Abstract

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru-Rh complex exhibits an electronic property different from those of the corresponding Ru-Ru and Rh-Rh complexes. The Ru-Rh complex can be decomposed in ionic liquids to metal nanoparticles.

Entities:  

Year:  2018        PMID: 29774331     DOI: 10.1039/c8dt01455h

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Introduction of plumbole to f-element chemistry.

Authors:  Luca Münzfeld; Xiaofei Sun; Sören Schlittenhardt; Christoph Schoo; Adrian Hauser; Sebastian Gillhuber; Florian Weigend; Mario Ruben; Peter W Roesky
Journal:  Chem Sci       Date:  2021-12-10       Impact factor: 9.825

  1 in total

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