Literature DB >> 29767989

Metal-Free C(sp3)-H Allylation via Aryl Carboxyl Radicals Enabled by Donor-Acceptor Complex.

Yang Li1, Jing Zhang1, Defang Li1,2, Yiyun Chen1,2.   

Abstract

The first aryl carboxyl radical generation by the donor-acceptor complex with N-acyloxyphthalimides and Hantzsch esters is reported. Regio- and chemoselective C(sp3)-H bond allylation is enabled by aryl carboxyl radicals with visible light irradiation under mild and metal-free conditions.

Entities:  

Year:  2018        PMID: 29767989     DOI: 10.1021/acs.orglett.8b01172

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  4 in total

1.  Hydroesterification and difunctionalization of olefins with N-hydroxyphthalimide esters.

Authors:  Lingying Leng; Joseph M Ready
Journal:  ACS Catal       Date:  2021-10-27       Impact factor: 13.700

2.  Catalyst-Free Decarbonylative Trifluoromethylthiolation Enabled by Electron Donor-Acceptor Complex Photoactivation.

Authors:  Alexander Lipp; Shorouk O Badir; Ryan Dykstra; Osvaldo Gutierrez; Gary A Molander
Journal:  Adv Synth Catal       Date:  2021-05-19       Impact factor: 5.981

3.  Catalyst-Free Deaminative Functionalizations of Primary Amines by Photoinduced Single-Electron Transfer.

Authors:  Jingjing Wu; Phillip S Grant; Xiabing Li; Adam Noble; Varinder K Aggarwal
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-14       Impact factor: 15.336

4.  Synthetic Methods Driven by the Photoactivity of Electron Donor-Acceptor Complexes.

Authors:  Giacomo E M Crisenza; Daniele Mazzarella; Paolo Melchiorre
Journal:  J Am Chem Soc       Date:  2020-03-12       Impact factor: 15.419

  4 in total

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