Literature DB >> 29745940

A robust and unique iron(ii) mosaic-like MOF.

Estefania Fernandez-Bartolome1, José Santos, Saeed Khodabakhshi, Laura J McCormick, Simon J Teat, Cristina Saenz de Pipaon, Jose R Galan-Mascarós, Nazario Martín, Jose Sanchez Costa.   

Abstract

A novel extended triazole-based ligand (PM-Tria) has been synthesized and an unprecedented MOF 3D has serendipitously been formed by assembling iron(ii), PM-Tria ligand and fluoride anions. This MOF contains a perfectly linear one-dimensional {Fe(ii)-F}n bridging chain that shows an antiferromagnetic behaviour. Furthermore, the structure is compared with a 14th century mosaic found in the Alhambra Palace in Granada showing a surprising symmetry resemblance.

Entities:  

Year:  2018        PMID: 29745940     DOI: 10.1039/c8cc01561a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

Review 1.  Metalloporphyrin Metal-Organic Frameworks: Eminent Synthetic Strategies and Recent Practical Exploitations.

Authors:  Arash Ebrahimi; Lukáš Krivosudský
Journal:  Molecules       Date:  2022-08-02       Impact factor: 4.927

  1 in total

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