| Literature DB >> 29725837 |
Caidie Qin1, Xue Bai2, Yue Zhang3,4, Kai Gao1.
Abstract
A photoelectrochemical wire microelectrode was constructed based on the use of a TiO2 nanotube array with electrochemically deposited CdSe semiconductor. A strongly amplified photocurrent is generated on the sensor surface. The microsensor has a response in the 0.05-20 μM dopamine (DA) concentration range and a 16.7 μM detection limit at a signal-to-noise ratio of 3. Sensitivity, recovery and reproducibility of the sensor were validated by detecting DA in spiked human urine, and satisfactory results were obtained. Graphical abstract Schematic of a sensitive photoelectrochemical microsensor based on CdSe modified TiO2 nanotube array. The photoelectrochemical microsensor was successfully applied to the determination of dopamine in urine samples.Entities:
Keywords: Dopamine; Electron-hole pairs seperation; Photocalysis; TiO2 nanotube array
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Year: 2018 PMID: 29725837 DOI: 10.1007/s00604-018-2788-4
Source DB: PubMed Journal: Mikrochim Acta ISSN: 0026-3672 Impact factor: 5.833