| Literature DB >> 29719108 |
Amanda F Baxter1, Jonas Schaab1, Karl O Christe1, Ralf Haiges1.
Abstract
The first X-ray crystal structure of an α-fluoroalcohol is reported. Heptafluorocyclobutanol was obtained in quantitative yield from hexafluorocyclobutanone by HF addition in anhydrous hydrogen fluoride. The compound was characterized by its X-ray single crystal structure. Heptafluorocyclobutanol readily undergoes hydrolysis to hexafluorocyclobutane-1,1-diol, which was also structurally characterized by X-ray diffraction.Entities:
Keywords: hydrogen fluoride; perfluorinated alcohols; perfluorinated ketones; structure elucidation; α-fluorinated alcohols
Year: 2018 PMID： 29719108 DOI： 10.1002/anie.201804101
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336