Literature DB >> 29712386

A Scandium Carbide Endohedral Metallofullerene: (Sc2 C2 )@C84.

Chun-Ru Wang1, Tsutomu Kai1, Testuo Tomiyama1, Takuya Yoshida2, Yuji Kobayashi2, Eiji Nishibori3, Masaki Takata3, Makoto Sakata3, Hisanori Shinohara1.   

Abstract

Not Sc2 @C86 but Sc2 C2 @C84 : that is the conclusion of 13 C NMR spectroscopic and synchrotron X-ray powder diffraction studies on a new metallofullerene obtained by arc discharge of Sc2 O3 /graphite rods. The picture shows a schematic representation of the deduced structure, in which the novel scandium carbide cluster Sc2 C2 is encaged in D2d -C84 .
© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  carbides; cluster compounds; fullerenes; scandium; structure elucidation

Year:  2001        PMID： 29712386     DOI： 10.1002/1521-3773(20010119)40:2<397::AID-ANIE397>3.0.CO;2-3

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  Triangular Monometallic Cyanide Cluster Entrapped in Carbon Cage with Geometry-Dependent Molecular Magnetism.

Authors:  Fupin Liu; Cong-Li Gao; Qingming Deng; Xianjun Zhu; Aram Kostanyan; Rasmus Westerström; Song Wang; Yuan-Zhi Tan; Jun Tao; Su-Yuan Xie; Alexey A Popov; Thomas Greber; Shangfeng Yang
Journal:  J Am Chem Soc       Date:  2016-10-31       Impact factor: 15.419

2.  Methane as a Selectivity Booster in the Arc-Discharge Synthesis of Endohedral Fullerenes: Selective Synthesis of the Single-Molecule Magnet Dy2TiC@C80 and Its Congener Dy2TiC2@C80.

Authors:  Katrin Junghans; Christin Schlesier; Aram Kostanyan; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Sandra Schiemenz; Rasmus Westerström; Thomas Greber; Bernd Büchner; Alexey A Popov
Journal:  Angew Chem Int Ed Engl       Date:  2015-09-09       Impact factor: 15.336

3.  Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy-Oxide Clusterfullerene Dy2O@C82.

Authors:  Wei Yang; Georgios Velkos; Fupin Liu; Svetlana M Sudarkova; Yaofeng Wang; Jiaxin Zhuang; Hanning Zhang; Xiang Li; Xingxing Zhang; Bernd Büchner; Stanislav M Avdoshenko; Alexey A Popov; Ning Chen
Journal:  Adv Sci (Weinh)       Date:  2019-08-15       Impact factor: 16.806

4.  Capturing the Long-Sought Dy@C2v(5)-C80 via Benzyl Radical Stabilization.

Authors:  Xinyi Han; Jinpeng Xin; Yangrong Yao; Zhihui Liang; Yongfu Qiu; Muqing Chen; Shangfeng Yang
Journal:  Nanomaterials (Basel)       Date:  2022-09-22       Impact factor: 5.719

5.  Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc2 TiC@Ih -C80 , Sc2 TiC@D5h -C80 and Sc2 TiC2 @Ih -C80 : Metal Size Tuning of the Ti(IV) /Ti(III) Redox Potentials.

Authors:  Katrin Junghans; Kamran B Ghiassi; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Marilyn M Olmstead; Alan L Balch; Alexey A Popov
Journal:  Chemistry       Date:  2016-07-26       Impact factor: 5.236
  5 in total

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