Literature DB >> 29712321

High-Pressure Synthesis of γ-P3 N5 at 11 GPa and 1500 °C in a Multianvil Assembly: A Binary Phosphorus(V) Nitride with a Three-Dimensional Network Structure from PN4 Tetrahedra and Tetragonal PN5 Pyramids.

Kai Landskron1, Hubert Huppertz1, Jürgen Senker1, Wolfgang Schnick1.   

Abstract

Extreme reaction conditions lead to the synthesis of γ-P3 N5 . Its crystal structure, unlike that of the normal pressure modification α-P3 N5 , is not exclusively built from PN4 tetrahedra, but from both PN4 tetrahedra (blue) and tetragonal PN5 pyramids (red). A tetragonal PN5 pyramid structure element has not been observed previously.
© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  high-pressure chemistry; nitrides; phase transitions; phosphorus; solid-state structures

Year:  2001        PMID： 29712321     DOI： 10.1002/1521-3773(20010716)40:14<2643::AID-ANIE2643>3.0.CO;2-T

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  1 in total

1.  High-Pressure and High-Temperature Chemistry of Phosphorus and Nitrogen: Synthesis and Characterization of α- and γ-P3N5.

Authors:  Matteo Ceppatelli; Demetrio Scelta; Manuel Serrano-Ruiz; Kamil Dziubek; Fernando Izquierdo-Ruiz; J Manuel Recio; Gaston Garbarino; Volodymyr Svitlyk; Mohamed Mezouar; Maurizio Peruzzini; Roberto Bini
Journal:  Inorg Chem       Date:  2022-07-26       Impact factor: 5.436
  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.