| Literature DB >> 29712308 |
Christopher A Hunter1, Caroline M R Low2, Martin J Packer1, Sharon E Spey1, Jeremy G Vinter2, Myroslav O Vysotsky1, Cristiano Zonta1.
Abstract
Reversible zinc-pyridine coordination and hydrogen-bonding interactions have been used to assemble a [2]rotaxane from three components. Cooperativity in the macrocyclization process that results in the porphyrin dimer makes the system exceptionally stable. However, the kinetic lability of the zinc-porphyrin interaction means the dimer is in dynamic equilibrium with its monomer, and this has been exploited in the construction of a [2]rotaxane.Entities:
Keywords: hydrogen bonds; noncovalent interactions; porphyrinoids; rotaxanes; supramolecular chemistry
Year: 2001 PMID： 29712308 DOI： 10.1002/1521-3773(20010716)40:14<2678::AID-ANIE2678>3.0.CO;2-U
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336