Literature DB >> 29712258

1,6-Methano[10]annulene has a Delocalized Structure in S0 and S1 : High-Resolution Spectroscopy in a Supersonic Jet.

Reinhold Seiler1, Bernhard Dick1.   

Abstract

For the ground state of the Hückel aromatic ring 1,6-methano[10]annulene (MA) both a localized and a delocalized structure have been proposed in the past, depending on the theoretical methods used. A high-resolution electronic spectrum in a supersonic jet unambiguously shows that isolated, ultracold MA has a delocalized structure in its S0 ground state as well as in its S1 excited state.
© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  VB methods; aromaticity ; delocalization ; laser spectroscopy

Year:  2001        PMID： 29712258     DOI： 10.1002/1521-3773(20011105)40:21<4020::AID-ANIE4020>3.0.CO;2-G

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Tenfold Metalation of Ferrocene: Synthesis, Structures, and Metallophilic Interactions in FeC10 (HgX)10.

Authors:  Susanne Margot Rupf; Gabriel Schröder; Robin Sievers; Moritz Malischewski
Journal:  Chemistry       Date:  2021-02-22       Impact factor: 5.236

2.  Synergic Deprotonation Generates Alkali-Metal Salts of Tethered Fluorenide-NHC Ligands Co-Complexed to Alkali-Metal Amides.

Authors:  Kieren J Evans; Stephen M Mansell
Journal:  Chemistry       Date:  2019-02-19       Impact factor: 5.236

Review 3.  Structural Motifs of Alkali Metal Superbases in Non-coordinating Solvents.

Authors:  Jan Klett
Journal:  Chemistry       Date:  2020-11-09       Impact factor: 5.020
  3 in total

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