| Literature DB >> 29712125 |
Euro Solari1, Carlos Da Silva1, Barbara Iacono1, Joëlle Hesschenbrouck1, Corrado Rizzoli2, Rosario Scopelliti3, Carlo Floriani3.
Abstract
Photoinduced cleavage of the residual N-N bond in the dimetallahydrazone 1 (Mes=2,4,6-Me3 C6 H2 ) led to a transient monomeric nitrido complex, which reacts further with 1 to form 2. Compound 1 was synthesized by the reductive arylation of MoCl4 ⋅DME by MesMgBr under an N2 atmosphere.Entities:
Keywords: dinitrogen ; molybdenum ; nitrides ; photochemistry
Year: 2001 PMID： 29712125 DOI： 10.1002/1521-3773(20011015)40:20<3907::AID-ANIE3907>3.0.CO;2-#
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336