Literature DB >> 29712085

The XeCl+ Ion: [XeCl]+ [Sb2 F11 ].

Stefan Seidel1, Konrad Seppelt1.   

Abstract

Chlorine-fluorine exchange in XeF+ leads to the orange crystalline salt [XeCl]+ [Sb2 F11 ]- , which is stable below -10°C. Thus, the number of known noble gas monohalogen cations is now three and, as calculations show, is approaching the theoretically possible limit. The synthesis of other such compounds-with the exception of ArF+ , which remains a formidable task-seems unlikely.
Copyright © 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  ab initio calculations; chlorine; noble gas compounds; structure elucidation; xenon

Year:  2001        PMID: 29712085     DOI: 10.1002/1521-3773(20011119)40:22<4225::AID-ANIE4225>3.0.CO;2-3

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  2 in total

1.  Characterization of an organometallic xenon complex using NMR and IR spectroscopy.

Authors:  Graham E Ball; Tamim A Darwish; Spili Geftakis; Michael W George; Douglas J Lawes; Peter Portius; Jonathan P Rourke
Journal:  Proc Natl Acad Sci U S A       Date:  2005-01-27       Impact factor: 11.205

2.  Reactive p-block cations stabilized by weakly coordinating anions.

Authors:  Tobias A Engesser; Martin R Lichtenthaler; Mario Schleep; Ingo Krossing
Journal:  Chem Soc Rev       Date:  2015-11-27       Impact factor: 54.564

  2 in total

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