| Literature DB >> 29712085 |
Stefan Seidel1, Konrad Seppelt1.
Abstract
Chlorine-fluorine exchange in XeF+ leads to the orange crystalline salt [XeCl]+ [Sb2 F11 ]- , which is stable below -10°C. Thus, the number of known noble gas monohalogen cations is now three and, as calculations show, is approaching the theoretically possible limit. The synthesis of other such compounds-with the exception of ArF+ , which remains a formidable task-seems unlikely.Entities:
Keywords: ab initio calculations; chlorine; noble gas compounds; structure elucidation; xenon
Year: 2001 PMID: 29712085 DOI: 10.1002/1521-3773(20011119)40:22<4225::AID-ANIE4225>3.0.CO;2-3
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336