Literature DB >> 29712010

A Heterogeneous cis-Dihydroxylation Catalyst with Stable, Site-Isolated Osmium-Diolate Reaction Centers.

An Severeyns1, Dirk E De Vos1, Lucien Fiermans2, Francis Verpoort3, Piet J Grobet1, Pierre A Jacobs1.   

Abstract

Involatile OsO4 ! A tetrasubstituted olefin is immobilized on SiO2 and reacts with OsO4 to form a stable osmate(IV) ester, which is a leak-proof heterogeneous catalyst for the cis-dihydroxylation of olefins.
Copyright © 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  dihydroxylation; heterogeneous catalysis; immobilization; osmium; oxidations

Year:  2001        PMID: 29712010     DOI: 10.1002/1521-3773(20010202)40:3<586::AID-ANIE586>3.0.CO;2-L

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  Boosting Thermal Stability of Volatile Os Catalysts by Downsizing to Atomically Dispersed Species.

Authors:  Jae Hyung Kim; Sinmyung Yoon; Du San Baek; Jihun Kim; Jinjong Kim; Kwangjin An; Sang Hoon Joo
Journal:  JACS Au       Date:  2022-05-26
  1 in total

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