Literature DB >> 29711987

Tandem Intramolecular Alkyne Silylformylation-Allylsilylation: A Case of Remote 1,5-Asymmetric Induction.

Steven J O'Malley1, James L Leighton1.   

Abstract

Two new C-C bonds as well as a remote stereocenter are formed in the title reaction. With remarkable efficiency, this new reaction provides, through remote 1,5-asymmetric induction, anti-1,5 diols that are useful synthons for polyol synthesis (see scheme; Hacac=acetylacetone).
© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  allylation; asymmetric induction; carbonylation; domino reactions; silylformylation

Year:  2001        PMID： 29711987     DOI： 10.1002/1521-3773(20010803)40:15<2915::AID-ANIE2915>3.0.CO;2-9

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  2 in total

1.  Diastereoselective temporary silicon-tethered ring-closing-metathesis reactions with prochiral alcohols: a new approach to long-range asymmetric induction.

Authors:  P Andrew Evans; Jian Cui; Gerald P Buffone
Journal:  Angew Chem Int Ed Engl       Date:  2003-04-17       Impact factor: 15.336

2.  Silylation reactions on nanoporous gold via homolytic Si-H activation of silanes.

Authors:  Hongbo Li; Huifang Guo; Zhiwen Li; Cai Wu; Jing Li; Chunliang Zhao; Shuangxi Guo; Yi Ding; Wei He; Yadong Li
Journal:  Chem Sci       Date:  2018-04-30       Impact factor: 9.825
  2 in total

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