Literature DB >> 29711828

Bi4 Te44+ -A Cube-Shaped, Polycationic Main Group Element Cluster.

Johannes Beck1, Michael Dolg2, Stefan Schlüter1.   

Abstract

Two valence electrons more than in square-antiprismatic 38-electron clusters such as Bi82+ or Sn86- : This is the reason for the unusual cube-shaped structure of the cation Bi4 Te44+ , which is obtained as the chloroaluminate salt from acidic AlCl3 /Na[AlCl4 ] melts.
© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  ab initio calculations; bismuth; cluster compounds; polycations; tellurium

Year:  2001        PMID： 29711828     DOI： 10.1002/1521-3773(20010618)40:12<2287::AID-ANIE2287>3.0.CO;2-M

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

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3.  First experimental evidence for the elusive tetrahedral cations [EP3]+ (E = S, Se, Te) in the condensed phase.

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Journal:  Chem Sci       Date:  2019-10-07       Impact factor: 9.825

4.  Metal Assisted Synthesis of Cationic Sulfidobismuth Cubanes in Ionic Liquids.

Authors:  Maximilian Knies; Matthias F Groh; Tobias Pietsch; Mai Lê Anh; Michael Ruck
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  4 in total

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