Literature DB >> 29711806

Separation of a Racemic Mixture of Two-Dimensional Molecular Clusters by Scanning Tunneling Microscopy.

Matthias Böhringer1, Karina Morgenstern1, Wolf-Dieter Schneider1, Richard Berndt2.   

Abstract

Adsorption of sub-monolayer amounts of 1-nitronaphthalene (NN) onto Au(111) leads to the aggregation of NN decamers, which exhibit two-dimensional chirality and represent a racemic mixture. In analogy to Pasteur's experiment of 1848 a scanning tunneling microscope can be used to discriminate and separate the enantiomers on a molecular scale. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Chirality; Enantiomeric resolution; Nanostructures; Scanning tunneling microscopy

Year:  1999        PMID： 29711806     DOI： 10.1002/(SICI)1521-3773(19990315)38:6<821::AID-ANIE821>3.0.CO;2-A

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  Assigning the absolute configuration of single aliphatic molecules by visual inspection.

Authors:  Daniel Ebeling; Marina Šekutor; Marvin Stiefermann; Jalmar Tschakert; Jeremy E P Dahl; Robert M K Carlson; André Schirmeisen; Peter R Schreiner
Journal:  Nat Commun       Date:  2018-06-20       Impact factor: 14.919

2.  Long-Range Chirality Recognition of a Polar Molecule on Au(111).

Authors:  Huihui Kong; Yinyue Qian; Xinbang Liu; Xinling Wan; Saeed Amirjalayer; Harald Fuchs
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-19       Impact factor: 15.336

Review 3.  Application of Crystalline Matrices for the Structural Determination of Organic Molecules.

Authors:  Ashley D Cardenal; Timothy R Ramadhar
Journal:  ACS Cent Sci       Date:  2021-02-17       Impact factor: 14.553

4.  Transferring axial molecular chirality through a sequence of on-surface reactions.

Authors:  Néstor Merino-Díez; Mohammed S G Mohammed; Jesús Castro-Esteban; Luciano Colazzo; Alejandro Berdonces-Layunta; James Lawrence; J Ignacio Pascual; Dimas G de Oteyza; Diego Peña
Journal:  Chem Sci       Date:  2020-04-29       Impact factor: 9.825

5.  Single-molecule insights into surface-mediated homochirality in hierarchical peptide assembly.

Authors:  Yumin Chen; Ke Deng; Shengbin Lei; Rong Yang; Tong Li; Yuantong Gu; Yanlian Yang; Xiaohui Qiu; Chen Wang
Journal:  Nat Commun       Date:  2018-07-13       Impact factor: 14.919
  5 in total

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