| Literature DB >> 29711782 |
François Simal1, Albert Demonceau1, Alfred F Noels1.
Abstract
A new set of ruthenium complexes such as 1 and 2 (the Grubbs ruthenium-carbene complex) has been shown to mediate the controlled atom-transfer radical polymerization (ATRP) of vinyl monomers with exceptional efficiency. Furthermore, there is a striking parallelism between the catalytic activity of these compounds in olefin metathesis and in ATRP. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: P ligands; Polymerizations; Radical reactions; Ruthenium
Year: 1999 PMID: 29711782 DOI: 10.1002/(SICI)1521-3773(19990215)38:4<538::AID-ANIE538>3.0.CO;2-W
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336