| Literature DB >> 29711659 |
Klaus Köllisch1, Wolfgang Schnick1.
Abstract
A rarity in solid-state chemistry is octahedrally coordinated silicon. Ce16 Si15 O6 N32 is the first nitridosilicate with this structural motif. Most oxosilicates containing octahedrally coordinated silicon are high-pressure phases. In contrast to that Ce16 Si15 O6 N32 has been synthesized under ambient pressure. An SiN6 octahedron that is surrounded by two parallel rings formed from six Si(O,N)4 tetrahedra is depicted. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Materials science; Nitridosilicates; Silicon; Solid-state chemistry; Structure elucidation
Year: 1999 PMID： 29711659 DOI： 10.1002/(SICI)1521-3773(19990201)38:3<357::AID-ANIE357>3.0.CO;2-D
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336