| Literature DB >> 29711652 |
Miriam Karni1, Yitzhak Apeloig1, Detlef Schröder2, Waltraud Zummack2, Roberto Rabezzana2, Helmut Schwarz2.
Abstract
Neutralization of [C,H,Si,X] .+ radical cations (X=F, Cl) in conjunction with electronic structure calculations provides the first experimental evidence for the formation of the neutral silynes HC≡SiF and HC≡SiCl, which have nonlinear structures (see picture). © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Ab initio calculations; Mass spectrometry; Silicon; Silynes
Year: 1999 PMID： 29711652 DOI： 10.1002/(SICI)1521-3773(19990201)38:3<331::AID-ANIE331>3.0.CO;2-8
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336