| Literature DB >> 29711646 |
Abstract
Which nucleophiles are capable of attacking the allyl ligand of the Pd-stabilized allyl cation 1? This question is answered by the electrophilicity parameter of 1 which is derived from kinetic investigations. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Keywords: Allyl complexes; Carbocations; Kinetics; Palladium; Reaction mechanisms
Year: 1999 PMID： 29711646 DOI： 10.1002/(SICI)1521-3773(19990201)38:3<343::AID-ANIE343>3.0.CO;2-X
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336