Literature DB >> 29711639

Sharpless Asymmetric Aminohydroxylation: Scope, Limitations, and Use in Synthesis.

Peter O'Brien1.   

Abstract

As a valuable methodology for organic synthesis, asymmetric aminohydroxylation (AA)-the catalytic and asymmetric conversion of alkenes into enantiomerically enriched N-protected amino alcohols-has become established in a remarkably short period of time. Examples of the types of products that can be synthesized easily on a reasonably large scale and in enantiomerically pure form are shown in the picture. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Amino alcohols; Aminohydroxylations; Asymmetric catalysis; Asymmetric synthesis; Osmium

Year:  1999        PMID: 29711639     DOI: 10.1002/(SICI)1521-3773(19990201)38:3<326::AID-ANIE326>3.0.CO;2-T

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  12 in total

1.  N-Nosyl Oxaziridines as Terminal Oxidants in Copper(II)-Catalyzed Olefin Oxyaminations.

Authors:  Sandra M Deporter; Ashley C Jacobsen; Katherine M Partridge; Kevin S Williamson; Tehshik P Yoon
Journal:  Tetrahedron Lett       Date:  2010-10-06       Impact factor: 2.415

2.  Photocatalytic Oxyamination of Alkenes: Copper(II) Salts as Terminal Oxidants in Photoredox Catalysis.

Authors:  Nicholas L Reed; Madeline I Herman; Vladimir P Miltchev; Tehshik P Yoon
Journal:  Org Lett       Date:  2018-11-08       Impact factor: 6.005

3.  Directed, Palladium(II)-Catalyzed Intermolecular Aminohydroxylation of Alkenes Using a Mild Oxidation System.

Authors:  Tian Zeng; Zhen Liu; Michael A Schmidt; Martin D Eastgate; Keary M Engle
Journal:  Org Lett       Date:  2018-06-11       Impact factor: 6.005

4.  Copper-Catalyzed 1,2-Amino Oxygenation of 1,3-Dienes: A Chemo-, Regio-, and Site-Selective Three-Component Reaction with O-Acylhydroxylamines and Carboxylic Acids.

Authors:  Brett N Hemric; Andy W Chen; Qiu Wang
Journal:  ACS Catal       Date:  2019-09-24       Impact factor: 13.084

5.  Copper-Catalyzed Modular Amino Oxygenation of Alkenes: Access to Diverse 1,2-Amino Oxygen-Containing Skeletons.

Authors:  Brett N Hemric; Andy W Chen; Qiu Wang
Journal:  J Org Chem       Date:  2019-01-17       Impact factor: 4.354

6.  Ligand Controlled Ir-Catalyzed Regiodivergent Oxyamination of Unactivated Alkenes.

Authors:  Honghui Lei; John H Conway; Caleb C Cook; Tomislav Rovis
Journal:  J Am Chem Soc       Date:  2019-07-16       Impact factor: 15.419

7.  Oxidative allene amination for the synthesis of nitrogen-containing heterocycles.

Authors:  Josephine Eshon; Nels C Gerstner; Jennifer M Schomaker
Journal:  ARKIVOC       Date:  2018-11-26       Impact factor: 1.140

8.  Iron catalyzed asymmetric oxyamination of olefins.

Authors:  Kevin S Williamson; Tehshik P Yoon
Journal:  J Am Chem Soc       Date:  2012-07-23       Impact factor: 15.419

9.  Alkene Syn- and Anti-Oxyamination with Malonoyl Peroxides.

Authors:  Jonathan M Curle; Marina C Perieteanu; Philip G Humphreys; Alan R Kennedy; Nicholas C O Tomkinson
Journal:  Org Lett       Date:  2020-01-30       Impact factor: 6.005

10.  Amino Alcohols from Eugenol as Potential Semisynthetic Insecticides: Chemical, Biological, and Computational Insights.

Authors:  Renato B Pereira; Nuno F S Pinto; Maria José G Fernandes; Tatiana F Vieira; Ana Rita O Rodrigues; David M Pereira; Sérgio F Sousa; Elisabete M S Castanheira; A Gil Fortes; M Sameiro T Gonçalves
Journal:  Molecules       Date:  2021-10-31       Impact factor: 4.411

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