| Literature DB >> 29711635 |
Achim Fischer1, Tamas Mallat1, Alfons Baiker1.
Abstract
Enhancements in selectivity by a factor of 4 to 18 were observed in the near critical regions of ammonia during the Co- and Ni-catalyzed synthesis of 1,3-diaminopropanes. These results are attributed to the higher concentration of ammonia at the surface of the catalyst, which favors the amination and suppresses degredation reactions. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Aminations; Ammonia; Diols; Heterogeneous catalysis; Supercritical fluids
Year: 1999 PMID： 29711635 DOI： 10.1002/(SICI)1521-3773(19990201)38:3<351::AID-ANIE351>3.0.CO;2-0
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336