Literature DB >> 29711582

[Ph2 P(NSiMe3 )]2 CLi2 : A Dilithium Dianionic Methanide Salt with an Unusual Li4 C2 Cluster Structure.

Aparna Kasani1, Ruppa P Kamalesh Babu1, Robert McDonald1, Ronald G Cavell1.   

Abstract

Four lithium atoms in a square-planar arrangement are capped by two carbon atoms and encapsulated by NSiMe3 chelation in the dilithium methanide salt 1. This air- and moisture-sensitive complex is formed by the reaction of CH2 (Ph2 P=NSiMe3 )2 with alkyl- or aryllithium reagents. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Cluster compounds; Lithium; N ligands; Phosphanimines; Phosphoranimines

Year:  1999        PMID： 29711582     DOI： 10.1002/(SICI)1521-3773(19990517)38:10<1483::AID-ANIE1483>3.0.CO;2-D

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Diphenyl[2-(phenyl-sulfon-yl)propan-2-yl]-λ(5)-phosphane-thione.

Authors:  Viktoria H Gessner
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-03-14

2.  Isolation and structure determination of a tetrameric sulfonyl dilithio methandiide in solution based on crystal structure analysis and 6Li/13C NMR spectroscopic data.

Authors:  Jürgen Vollhardt; Hans Jörg Lindner; Hans-Joachim Gais
Journal:  Beilstein J Org Chem       Date:  2020-08-21       Impact factor: 2.883

3.  Reappraising Schmidpeter's bis(iminophosphoranyl)phosphides: coordination to transition metals and bonding analysis.

Authors:  Adrien T Normand; E Daiann Sosa Carrizo; Corentin Magnoux; Esteban Lobato; Hélène Cattey; Philippe Richard; Stéphane Brandès; Charles H Devillers; Anthony Romieu; Pierre Le Gendre; Paul Fleurat-Lessard
Journal:  Chem Sci       Date:  2020-10-26       Impact factor: 9.825
  3 in total

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