Literature DB >> 29711566

Self-Assembly of a Molecular Floral Lace with One-Dimensional Channels and Inclusion of Glucose.

Hye Jin Choi1, Taek Soon Lee1, Myunghyun Paik Suh1.   

Abstract

A three-dimensional network with one-dimensional channels (see picture) has been self-assembled from the nickel(II) complex of cyclam and 1,3,5-benzenetricarboxylate in water through hydrogen-bond formation. The channels have an appropriate diameter (10.3 Å) to include D-glucose with a formation constant of Kf =(1.38±0.01)×104  M-1 . Under similar conditions maltose is not included. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Crystal engineering; Host-guest chemistry; Inclusion compounds; Macrocycles; Supramolecular chemistry

Year:  1999        PMID: 29711566     DOI: 10.1002/(SICI)1521-3773(19990517)38:10<1405::AID-ANIE1405>3.0.CO;2-H

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  One-dimensional hydrogen-bonded infinite chain from nickel(II) tetraaza macrocyclic complex and 1,2-cyclopentanedicarboxylate ligand.

Authors:  In-Taek Lim; Ki-Young Choi
Journal:  Int J Mol Sci       Date:  2011-04-01       Impact factor: 5.923

  1 in total

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