Literature DB >> 29711497

A Simple Preparative Route to Bis(imido)uranium(VI) Complexes by the Direct Reductions of Diazenes and Azides.

Benjamin P Warner1, Brian L Scott1, Carol J Burns1.   

Abstract

In clean, one-pot procedures, the uranium complex 1 reductively cleaves azides and azo compounds to generate bis(imido) derivatives [Eq. (a)]. This unusual reaction has not been observed previously in either the actinide series or with a metallocene complex. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Actinides; Azo compounds; F orbitals; Imido compounds; Uranium

Year:  1998        PMID： 29711497     DOI： 10.1002/(SICI)1521-3773(19980420)37:7<959::AID-ANIE959>3.0.CO;2-D

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Mechanistic insight into N=N cleavage by a low-coordinate iron(II) hydride complex.

Authors:  Azwana R Sadique; Elizabeth A Gregory; William W Brennessel; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2007-06-12       Impact factor: 15.419

2.  Single metal four-electron reduction by U(ii) and masked "U(ii)" compounds.

Authors:  Dieuwertje K Modder; Chad T Palumbo; Iskander Douair; Rosario Scopelliti; Laurent Maron; Marinella Mazzanti
Journal:  Chem Sci       Date:  2021-03-22       Impact factor: 9.825

3.  Divergent uranium- versus phosphorus-based reduction of Me3SiN3 with steric modification of phosphido ligands.

Authors:  Robert J Ward; Pokpong Rungthanaphatsophon; Iker Del Rosal; Steven P Kelley; Laurent Maron; Justin R Walensky
Journal:  Chem Sci       Date:  2020-05-27       Impact factor: 9.825

4.  Evidence for single metal two electron oxidative addition and reductive elimination at uranium.

Authors:  Benedict M Gardner; Christos E Kefalidis; Erli Lu; Dipti Patel; Eric J L McInnes; Floriana Tuna; Ashley J Wooles; Laurent Maron; Stephen T Liddle
Journal:  Nat Commun       Date:  2017-12-01       Impact factor: 14.919
  4 in total

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