| Literature DB >> 29711490 |
Margarete K Leclerc1, Robert M Waymouth1.
Abstract
A small variation in the substituent R' on the metallocene catalyst employed in the copolymerization of ethene and propene leads to a highly alternating (81-83%) structure (1) rather than a statistical copolymer. Such copolymers were until recently only accessible by hydrogenation of polyisoprene or 1,4-poly(pentadiene). © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Alkenes; Copolymerizations; Homogeneous catalysis; Polymers; Sandwich complexes
Year: 1998 PMID: 29711490 DOI: 10.1002/(SICI)1521-3773(19980420)37:7<922::AID-ANIE922>3.0.CO;2-G
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336