Literature DB >> 29711490

Alternating Ethene/Propene Copolymerization with a Metallocene Catalyst.

Margarete K Leclerc1, Robert M Waymouth1.   

Abstract

A small variation in the substituent R' on the metallocene catalyst employed in the copolymerization of ethene and propene leads to a highly alternating (81-83%) structure (1) rather than a statistical copolymer. Such copolymers were until recently only accessible by hydrogenation of polyisoprene or 1,4-poly(pentadiene). © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Alkenes; Copolymerizations; Homogeneous catalysis; Polymers; Sandwich complexes

Year:  1998        PMID: 29711490     DOI: 10.1002/(SICI)1521-3773(19980420)37:7<922::AID-ANIE922>3.0.CO;2-G

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  Isotactic and Syndiotactic Alternating Ethylene/Propylene Copolymers Obtained Through Non-Catalytic Hydrogenation of Highly Stereoregular cis-1,4 Poly(1,3-diene)s.

Authors:  Giovanni Ricci; Antonella Caterina Boccia; Giuseppe Leone; Ivana Pierro; Giorgia Zanchin; Miriam Scoti; Finizia Auriemma; Claudio De Rosa
Journal:  Molecules       Date:  2017-05-06       Impact factor: 4.411

  1 in total

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