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Literature DB >> 29711456

From Structural Models of Galactose Oxidase to Homogeneous Catalysis: Efficient Aerobic Oxidation of Alcohols.

Phalguni Chaudhuri¹, Martina Hess¹, Ulrich Flörke², Karl Wieghardt¹.

Abstract

Two reaction pathways are catalyzed by the dinuclear copper(II)-phenoxyl complex 1-a functional model for the metalloenzyme galactose oxidase-by the oxidation of primary and secondary alcohols with dioxygen (air) in homogeneous solution to their corresponding aldehydes or ketones and/or 1,2-glycols (oxidative C-C coupling). The reduction product formed is H2 O2 , not water. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities: Chemical

Keywords: Alcohols; Copper; Galactose oxidase; Homogeneous catalysis; Metalloenzymes

Year: 1998 PMID： 29711456 DOI： 10.1002/(SICI)1521-3773(19980904)37:16<2217::AID-ANIE2217>3.0.CO;2-D

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

9 in total

Review 1. Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O₂ Model Systems to Organometallic Transformations.

Authors: Rachel Trammell; Khashayar Rajabimoghadam; Isaac Garcia-Bosch
Journal: Chem Rev Date: 2019-01-30 Impact factor: 60.622

Review 2. Heteroligand Metal Complexes with Extended Redox Properties Based on Redox-Active Chelating Ligands of o-Quinone Type and Ferrocene.

Authors: Svetlana V Baryshnikova; Andrey I Poddel'sky
Journal: Molecules Date: 2022-06-19 Impact factor: 4.927

3. Characterization of the one-electron oxidized Cu(II)-salen complexes with a side chain aromatic ring: the effect of the indole ring on the Cu(II)-phenoxyl radical species.

Authors: Hiromi Oshita; Takayoshi Yoshimura; Seiji Mori; Fumito Tani; Yuichi Shimazaki; Osamu Yamauchi
Journal: J Biol Inorg Chem Date: 2017-12-07 Impact factor: 3.358

Review 4. Using nature's blueprint to expand catalysis with Earth-abundant metals.

Authors: R Morris Bullock; Jingguang G Chen; Laura Gagliardi; Paul J Chirik; Omar K Farha; Christopher H Hendon; Christopher W Jones; John A Keith; Jerzy Klosin; Shelley D Minteer; Robert H Morris; Alexander T Radosevich; Thomas B Rauchfuss; Neil A Strotman; Aleksandra Vojvodic; Thomas R Ward; Jenny Y Yang; Yogesh Surendranath
Journal: Science Date: 2020-08-14 Impact factor: 47.728

5. Electronic structure analysis of electrochemical CO₂ reduction by iron-porphyrins reveals basic requirements for design of catalysts bearing non-innocent ligands.

Authors: Maxime Tarrago; Shengfa Ye; Frank Neese
Journal: Chem Sci Date: 2022-06-29 Impact factor: 9.969

6. Revealing the thermodynamic driving force for ligand-based reductions in quinoids; conceptual rules for designing redox active and non-innocent ligands.

Authors: G Skara; B Pinter; P Geerlings; F De Proft
Journal: Chem Sci Date: 2015-05-01 Impact factor: 9.825

From Structural Models of Galactose Oxidase to Homogeneous Catalysis: Efficient Aerobic Oxidation of Alcohols.

Review 1. Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O₂ Model Systems to Organometallic Transformations.

Review 2. Heteroligand Metal Complexes with Extended Redox Properties Based on Redox-Active Chelating Ligands of o-Quinone Type and Ferrocene.

3. Characterization of the one-electron oxidized Cu(II)-salen complexes with a side chain aromatic ring: the effect of the indole ring on the Cu(II)-phenoxyl radical species.

Review 4. Using nature's blueprint to expand catalysis with Earth-abundant metals.

5. Electronic structure analysis of electrochemical CO₂ reduction by iron-porphyrins reveals basic requirements for design of catalysts bearing non-innocent ligands.

6. Revealing the thermodynamic driving force for ligand-based reductions in quinoids; conceptual rules for designing redox active and non-innocent ligands.

Review 7. Copper catalysis with redox-active ligands.

8. Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands.

9. Optimizing Group Transfer Catalysis by Copper Complex with Redox-Active Ligand in an Entatic State.

From Structural Models of Galactose Oxidase to Homogeneous Catalysis: Efficient Aerobic Oxidation of Alcohols.

Review 1. Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations.

Review 2. Heteroligand Metal Complexes with Extended Redox Properties Based on Redox-Active Chelating Ligands of o-Quinone Type and Ferrocene.

3. Characterization of the one-electron oxidized Cu(II)-salen complexes with a side chain aromatic ring: the effect of the indole ring on the Cu(II)-phenoxyl radical species.

Review 4. Using nature's blueprint to expand catalysis with Earth-abundant metals.

5. Electronic structure analysis of electrochemical CO2 reduction by iron-porphyrins reveals basic requirements for design of catalysts bearing non-innocent ligands.

6. Revealing the thermodynamic driving force for ligand-based reductions in quinoids; conceptual rules for designing redox active and non-innocent ligands.

Review 7. Copper catalysis with redox-active ligands.

8. Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands.

9. Optimizing Group Transfer Catalysis by Copper Complex with Redox-Active Ligand in an Entatic State.

Review 1. Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O₂ Model Systems to Organometallic Transformations.

5. Electronic structure analysis of electrochemical CO₂ reduction by iron-porphyrins reveals basic requirements for design of catalysts bearing non-innocent ligands.