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Literature DB >> 29711431

The First Coordinatively Saturated, Quadruply Stranded Helicate and Its Encapsulation of a Hexafluorophosphate Anion.

Abstract

Incarcerated in a helical prison: The encapsulation of a PF6- ion within a quadruply stranded helicate (shown schematically) results from the self-assembly of four molecules of 1,4-bis(3-pyridyloxy)benzene and two PdII ions. This represents not only the first example of a coordinatively saturated quadruple helicate, but also the first example of the encapsulation of a complex anion by a helicate. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities: Chemical Gene

Keywords: Helical structures; Host-guest chemistry; N ligands; Palladium; Supramolecular chemistry

Year: 1998 PMID： 29711431 DOI： 10.1002/(SICI)1521-3773(19981217)37:23<3295::AID-ANIE3295>3.0.CO;2-5

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

9 in total

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Authors: Tomasz K Piskorz; Vicente Martí-Centelles; Tom A Young; Paul J Lusby; Fernanda Duarte
Journal: ACS Catal Date: 2022-05-02 Impact factor: 13.700

3. Nitrogen heterocycles as building blocks for new metallosupramolecular architectures.

Authors: Peter J Steel
Journal: Molecules Date: 2004-05-31 Impact factor: 4.411

4. Synthesis and characterisation of eight isomeric bis(2-pyridyloxy)naphthalenes.

Authors: Brendan J O'Keefe; Peter J Steel
Journal: Molecules Date: 2006-09-13 Impact factor: 4.411

5. Anticancer Activity and Cisplatin Binding Ability of Bis-Quinoline and Bis-Isoquinoline Derived [Pd₂L₄]⁴⁺ Metallosupramolecular Cages.

Authors: Roan A S Vasdev; Lachlan F Gaudin; Dan Preston; Jackmil P Jogy; Gregory I Giles; James D Crowley
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The First Coordinatively Saturated, Quadruply Stranded Helicate and Its Encapsulation of a Hexafluorophosphate Anion.

Review 1. Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.

Review 2. Computational Modeling of Supramolecular Metallo-organic Cages-Challenges and Opportunities.

3. Nitrogen heterocycles as building blocks for new metallosupramolecular architectures.

4. Synthesis and characterisation of eight isomeric bis(2-pyridyloxy)naphthalenes.

5. Anticancer Activity and Cisplatin Binding Ability of Bis-Quinoline and Bis-Isoquinoline Derived [Pd₂L₄]⁴⁺ Metallosupramolecular Cages.

6. A chiral self-sorting photoresponsive coordination cage based on overcrowded alkenes.

7. Visible-Light-Responsive Self-Assembled Complexes: Improved Photoswitching Properties by Metal Ion Coordination.

8. Feeding a Molecular Squid: A Pliable Nanocarbon Receptor for Electron-Poor Aromatics.

Review 9. Structural Flexibility in Metal-Organic Cages.

The First Coordinatively Saturated, Quadruply Stranded Helicate and Its Encapsulation of a Hexafluorophosphate Anion.

Review 1. Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.

Review 2. Computational Modeling of Supramolecular Metallo-organic Cages-Challenges and Opportunities.

3. Nitrogen heterocycles as building blocks for new metallosupramolecular architectures.

4. Synthesis and characterisation of eight isomeric bis(2-pyridyloxy)naphthalenes.

5. Anticancer Activity and Cisplatin Binding Ability of Bis-Quinoline and Bis-Isoquinoline Derived [Pd2L4]4+ Metallosupramolecular Cages.

6. A chiral self-sorting photoresponsive coordination cage based on overcrowded alkenes.

7. Visible-Light-Responsive Self-Assembled Complexes: Improved Photoswitching Properties by Metal Ion Coordination.

8. Feeding a Molecular Squid: A Pliable Nanocarbon Receptor for Electron-Poor Aromatics.

Review 9. Structural Flexibility in Metal-Organic Cages.

5. Anticancer Activity and Cisplatin Binding Ability of Bis-Quinoline and Bis-Isoquinoline Derived [Pd₂L₄]⁴⁺ Metallosupramolecular Cages.