Literature DB >> 29711427

Ba3 Ge4 : Polymerization of Zintl Anions in the Solid and Bond Stretching Isomerism.

Fabio Zürcher1, Reinhard Nesper1.   

Abstract

Polymerizations in single crystals have rarely been described-in the case of the title compound they are even reversible. The rebuttoning of the bonds can be regarded as bond stretching isomerism, which is currently the subject of controversial discussion in many areas of chemistry. The geometrical arrangement of the monomeric Ge46- ions in the crystal is shown in the picture. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Electron localization function; Electronic structure; Solid-state chemistry; Zintl anions

Year:  1998        PMID: 29711427     DOI: 10.1002/(SICI)1521-3773(19981217)37:23<3314::AID-ANIE3314>3.0.CO;2-L

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  Bond-bending isomerism of Au2I3-: competition between covalent bonding and aurophilicity.

Authors:  Wan-Lu Li; Hong-Tao Liu; Tian Jian; Gary V Lopez; Zachary A Piazza; Dao-Ling Huang; Teng-Teng Chen; Jing Su; Ping Yang; Xin Chen; Lai-Sheng Wang; Jun Li
Journal:  Chem Sci       Date:  2015-10-13       Impact factor: 9.825

  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.