| Literature DB >> 29711427 |
Fabio Zürcher1, Reinhard Nesper1.
Abstract
Polymerizations in single crystals have rarely been described-in the case of the title compound they are even reversible. The rebuttoning of the bonds can be regarded as bond stretching isomerism, which is currently the subject of controversial discussion in many areas of chemistry. The geometrical arrangement of the monomeric Ge46- ions in the crystal is shown in the picture. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Electron localization function; Electronic structure; Solid-state chemistry; Zintl anions
Year: 1998 PMID: 29711427 DOI: 10.1002/(SICI)1521-3773(19981217)37:23<3314::AID-ANIE3314>3.0.CO;2-L
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336