| Literature DB >> 29711352 |
Markus Kinne1, Andreas Heidenreich2, Klaus Rademann1.
Abstract
Bismuth oxide cluster ions are reduced by propene in exactly the same way as solid bismuth oxide (Bi2 O3 ), which is used as a catalyst. Even in the case of the smallest bismuth oxide cluster ions, such as the Bi3 O4+ isomer shown in the picture, the supposedly unreactive bridging oxygen atom can participate in the alkene oxidation. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Ab initio calculations; Alkenes; Clusters; Heterogeneous catalysis; Oxidations
Year: 1998 PMID： 29711352 DOI： 10.1002/(SICI)1521-3773(19981002)37:18<2509::AID-ANIE2509>3.0.CO;2-S
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336