Literature DB >> 29711331

Multiple Ga-Ga Bonding Character in Na2 [Ga(GaTrip2 )3 ], and a Comparison with Neutral Ga(GaTrip2 )3 (Trip=2,4,6-iPr3 C6 H2 ).

Rudolf J Wehmschulte1, Philip P Power1.   

Abstract

Delocalized over the Ga4 framework, the two electrons are lost in the oxidation of Na2 [Ga(GaTrip2 )3 ] to Ga(GaTrip2 )3 . This leads to a lengthening of the Ga-Ga bond by about 0.08 Å. Ar=Trip=2,4,6-iPr3 C6 H2 . © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Gallium; Multiple bonds; Pi interactions

Year:  1998        PMID: 29711331     DOI: 10.1002/(SICI)1521-3773(19981204)37:22<3152::AID-ANIE3152>3.0.CO;2-7

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  Probing alkali metal-pi interactions with the side chain residue of tryptophan.

Authors:  Jiaxin Hu; Leonard J Barbour; George W Gokel
Journal:  Proc Natl Acad Sci U S A       Date:  2002-04-09       Impact factor: 11.205

  1 in total

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