Literature DB >> 29711298

A Surprising Solid-Phase Effect: Development of a Recyclable "Traceless" Linker System for Reactions on Solid Support.

Stefan Bräse1, Dieter Enders1, Johannes Köbberling1, Frank Avemaria1.   

Abstract

Triazenes as "traceless" linkers for solid-phase synthesis have been utilized for the attachment of arenes to a solid support and yield the corresponding products after various organometallic reactions (Heck reaction and asymmetric dihydroxylation, see the reaction scheme) and cycloadditions (Diels-Alder reaction). The triazene linker is distinguished by its accessibility, thermal robustness, and capability to undergo regeneration. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Arenes; Asymmetric synthesis; C-C coupling; Solid-phase synthesis; Triazenes

Year:  1998        PMID: 29711298     DOI: 10.1002/(SICI)1521-3773(19981231)37:24<3413::AID-ANIE3413>3.0.CO;2-K

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  2 in total

1.  Sequence-definition in stiff conjugated oligomers.

Authors:  Rebekka V Schneider; Kevin A Waibel; Andreas P Arndt; Mathias Lang; Rebecca Seim; Dmitry Busko; Stefan Bräse; Uli Lemmer; Michael A R Meier
Journal:  Sci Rep       Date:  2018-11-30       Impact factor: 4.379

2.  Synthesis of new pyrazolo[1,2,3]triazines by cyclative cleavage of pyrazolyltriazenes.

Authors:  Nicolai Wippert; Martin Nieger; Claudine Herlan; Nicole Jung; Stefan Bräse
Journal:  Beilstein J Org Chem       Date:  2021-11-22       Impact factor: 2.883

  2 in total

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