Literature DB >> 29711296

Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide.

Achim Müller1, Erich Krickemeyer1, Hartmut Bögge1, Marc Schmidtmann1, Frank Peters1.   

Abstract

Plato and Kepler would have been pleased. Despite the large number of atoms present the cluster anion 1 resembles an icosahedral-type structure. This represents definitively an unprecedented event in chemistry! The structure is made up of 12 {Mo11 } fragments such that the fivefold symmetry axes are retained in the resulting spherical object. As an inscribed icosahedron can be recognized in the spherical shell of 1 (see picture), similarities with Kepler's famous shell model of the cosmos can be seen. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Cage compounds; Clusters; Fullerenes; Polyoxometalates; Supramolecular chemistry

Year:  1998        PMID： 29711296     DOI： 10.1002/(SICI)1521-3773(19981231)37:24<3359::AID-ANIE3359>3.0.CO;2-J

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  13 in total

1.  Controlled drug delivery and cell adhesion for bone tissue regeneration by Keplerate polyoxometalate (Mo132)/metronidazole/PMMA scaffolds.

Authors:  Hamid Taghiyar; Bahram Yadollahi; Abolghasem Abbasi Kajani
Journal:  Sci Rep       Date:  2022-08-24       Impact factor: 4.996

2.  Automated Rational Design of Metal-Organic Polyhedra.

Authors:  Aleksandar Kondinski; Angiras Menon; Daniel Nurkowski; Feroz Farazi; Sebastian Mosbach; Jethro Akroyd; Markus Kraft
Journal:  J Am Chem Soc       Date:  2022-06-22       Impact factor: 16.383

3.  Embedding alkenes within an icosahedral inorganic fullerene {(NH4)42[Mo132O372(L)30(H2O)72]} for trapping volatile organics.

Authors:  Robert W Pow; Weimin Xuan; De-Liang Long; Nicola L Bell; Leroy Cronin
Journal:  Chem Sci       Date:  2020-01-23       Impact factor: 9.825

4.  Sizing and Discovery of Nanosized Polyoxometalate Clusters by Mass Spectrometry.

Authors:  Andrew J Surman; Philip J Robbins; Jakub Ujma; Qi Zheng; Perdita E Barran; Leroy Cronin
Journal:  J Am Chem Soc       Date:  2016-03-14       Impact factor: 15.419

5.  Exploring the Molecular Growth of Two Gigantic Half-Closed Polyoxometalate Clusters {Mo180 } and {Mo130 Ce6 }.

Authors:  Weimin Xuan; Robert Pow; De-Liang Long; Leroy Cronin
Journal:  Angew Chem Int Ed Engl       Date:  2017-06-01       Impact factor: 15.336

6.  Tellurite-Squarate Driven Assembly of a New Family of Nanoscale Clusters Based on (Mo2 O2 S2 )2.

Authors:  Jamie W Purcell; Haralampos N Miras; De-Liang Long; Panagiota Markopoulou; Leroy Cronin
Journal:  Chemistry       Date:  2017-06-29       Impact factor: 5.236

7.  Protective Effect of Polyoxometalates in {Mo132}/Maghemite Binary Superlattices Under Annealing.

Authors:  Romain Breitwieser; Adrien Garnier; Thomas Auvray; Anh-Tu Ngo; Benoit Baptiste; Nicolas Menguy; Anna Proust; Christophe Petit; Florence Volatron; Caroline Salzemann
Journal:  Front Chem       Date:  2019-11-29       Impact factor: 5.221

8.  A polymeric co-assembly of subunit vaccine with polyoxometalates induces enhanced immune responses.

Authors:  Xinpei Li; Xiaofeng He; Dongrong He; Yuan Liu; Kun Chen; Panchao Yin
Journal:  Nano Res       Date:  2021-12-14       Impact factor: 10.269

9.  Giant Spherical Cluster with I-C140 Fullerene Topology.

Authors:  Sebastian Heinl; Eugenia Peresypkina; Jörg Sutter; Manfred Scheer
Journal:  Angew Chem Int Ed Engl       Date:  2015-09-28       Impact factor: 15.336

10.  Spontaneous formation of autocatalytic sets with self-replicating inorganic metal oxide clusters.

Authors:  Haralampos N Miras; Cole Mathis; Weimin Xuan; De-Liang Long; Robert Pow; Leroy Cronin
Journal:  Proc Natl Acad Sci U S A       Date:  2020-05-05       Impact factor: 11.205
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