Literature DB >> 29711243

Anion-Templated Assembly of a Supramolecular Cage Complex.

James S Fleming1, Karen L V Mann1, Charles-Antoine Carraz1, Elefteria Psillakis1, John C Jeffery1, Jon A McCleverty1, Michael D Ward1.   

Abstract

The templating effect of the tetrafluoroborate ion leads to assembly of four CoII ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but with NiII a simpler dinuclear complex forms. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Bridging ligands; Self-assembly; Supramolecular chemistry; Template synthesis; Transition metals

Year:  1998        PMID： 29711243     DOI： 10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Q

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Anion-templated self-assembly of tetrahedral cage complexes of cobalt(II) with bridging ligands containing two bidentate pyrazolyl-pyridine binding sites.

Authors:  Rowena L Paul; Zöe R Bell; John C Jeffery; Jon A McCleverty; Michael D Ward
Journal:  Proc Natl Acad Sci U S A       Date:  2002-04-02       Impact factor: 11.205

Review 2.  Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.

Authors:  Charlie T McTernan; Jack A Davies; Jonathan R Nitschke
Journal:  Chem Rev       Date:  2022-04-18       Impact factor: 72.087

3.  Coordination-Cage-Catalysed Hydrolysis of Organophosphates: Cavity- or Surface-Based?

Authors:  Christopher G P Taylor; Alexander J Metherell; Stephen P Argent; Fatma M Ashour; Nicholas H Williams; Michael D Ward
Journal:  Chemistry       Date:  2020-02-06       Impact factor: 5.236

4.  Strong Affinity of Triazolium-Appended Dipyrromethenes (TADs) for BF4.

Authors:  Charles Guérin; Zhan Zhang; Ludivine Jean-Gérard; Stephan Steinmann; Carine Michel; Bruno Andrioletti
Journal:  Molecules       Date:  2020-10-05       Impact factor: 4.411
  4 in total

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