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Literature DB >> 29711236

Formation of a Ring-Shaped Reduced "Metal Oxide" with the Simple Composition [(MoO₃ )₁₇₆ (H₂ O)₈₀ H₃₂ ].

Achim Müller¹, Erich Krickemeyer¹, Hartmut Bögge¹, Marc Schmidtmann¹, Christian Beugholt¹, Paul Kögerler¹, Canzhong Lu¹.

Abstract

The largest inorganic molecular system so far, [(MoO3 )176 (H2 O)80 H32 ] (1; the picture on the right shows the polyhedral representation), which has been characterized by X-ray structure analysis, possesses a cavity of diameter 2.3 nm and remarkably shows the stoichiometry of a (reduced) protonated and hydrated "molecular molybdenum trioxide". It is formed by reduction of an aqueous solution of lithium molybdate with tin(II) chloride at very high H+ concentrations. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities: Chemical

Keywords: Inorganic rings; Molybdenum; Molybdenum blue; Polyoxometalates; Supramolecular chemistry

Year: 1998 PMID： 29711236 DOI： 10.1002/(SICI)1521-3773(19980518)37:9<1220::AID-ANIE1220>3.0.CO;2-G

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

5 in total

Review 1. Lanthanides Singing the Blues: Their Fascinating Role in the Assembly of Gigantic Molybdenum Blue Wheels.

Authors: Emir Al-Sayed; Annette Rompel
Journal: ACS Nanosci Au Date: 2022-03-02

2. Overcoming the Crystallization Bottleneck: A Family of Gigantic Inorganic {Pdx }(L) (x=84, 72) Palladium Macrocycles Discovered using Solution Techniques.

Authors: Lorna G Christie; Andrew J Surman; Rachel A Scullion; Feng Xu; De-Liang Long; Leroy Cronin
Journal: Angew Chem Int Ed Engl Date: 2016-09-16 Impact factor: 15.336

Formation of a Ring-Shaped Reduced "Metal Oxide" with the Simple Composition [(MoO₃ )₁₇₆ (H₂ O)₈₀ H₃₂ ].

Review 1. Lanthanides Singing the Blues: Their Fascinating Role in the Assembly of Gigantic Molybdenum Blue Wheels.

2. Overcoming the Crystallization Bottleneck: A Family of Gigantic Inorganic {Pdx }(L) (x=84, 72) Palladium Macrocycles Discovered using Solution Techniques.

3. Exploring the Molecular Growth of Two Gigantic Half-Closed Polyoxometalate Clusters {Mo₁₈₀ } and {Mo₁₃₀ Ce₆ }.

4. Human versus Robots in the Discovery and Crystallization of Gigantic Polyoxometalates.

5. Stereoselective Assembly of Gigantic Chiral Molybdenum Blue Wheels Using Lanthanide Ions and Amino Acids.

Formation of a Ring-Shaped Reduced "Metal Oxide" with the Simple Composition [(MoO3 )176 (H2 O)80 H32 ].

Review 1. Lanthanides Singing the Blues: Their Fascinating Role in the Assembly of Gigantic Molybdenum Blue Wheels.

2. Overcoming the Crystallization Bottleneck: A Family of Gigantic Inorganic {Pdx }(L) (x=84, 72) Palladium Macrocycles Discovered using Solution Techniques.

3. Exploring the Molecular Growth of Two Gigantic Half-Closed Polyoxometalate Clusters {Mo180 } and {Mo130 Ce6 }.

4. Human versus Robots in the Discovery and Crystallization of Gigantic Polyoxometalates.

5. Stereoselective Assembly of Gigantic Chiral Molybdenum Blue Wheels Using Lanthanide Ions and Amino Acids.

Formation of a Ring-Shaped Reduced "Metal Oxide" with the Simple Composition [(MoO₃ )₁₇₆ (H₂ O)₈₀ H₃₂ ].

3. Exploring the Molecular Growth of Two Gigantic Half-Closed Polyoxometalate Clusters {Mo₁₈₀ } and {Mo₁₃₀ Ce₆ }.