Literature DB >> 29711178

Dithioacetals as an Entry to Titanium-Alkylidene Chemistry: A New and Efficient Carbonyl Olefination.

Bernhard Breit1.   

Abstract

Wittig, Horner-Wadsworth-Emmons, Julia-Lythgoe, Tebbe, Grubbs, and Petasis-when it comes to carbonyl olefinations, these names are familiar to all chemistry students. In the future, the name Takeda will probably have to be added to this list. His recent work on the formation of titanium-alkylidene species from dithioacetals has provided organic chemists with a remarkable method for carbonyl olefination that is generally applicable under neutral to Lewis acidic conditions. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Alkylidene complexes; Olefinations; Synthetic methods; Titanium

Year:  1998        PMID: 29711178     DOI: 10.1002/(SICI)1521-3773(19980302)37:4<453::AID-ANIE453>3.0.CO;2-M

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  2 in total

1.  Reversed-Polarity Synthesis of Diaryl Ketones through Palladium-Catalyzed Direct Arylation of 2-Aryl-1,3-dithianes.

Authors:  Baris Yucel; Patrick J Walsh
Journal:  Adv Synth Catal       Date:  2014-11-24       Impact factor: 5.837

2.  Hydrazone and Oxime Olefination via Ruthenium Alkylidenes.

Authors:  Daniel J Nasrallah; Troy E Zehnder; Jacob R Ludwig; Daniel C Steigerwald; John J Kiernicki; Nathaniel K Szymczak; Corinna S Schindler
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-29       Impact factor: 16.823

  2 in total

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