| Literature DB >> 29711162 |
Abstract
A new radical approach to cyclic ethers 2 is offered by the intramolecular homolytic substitution (SH i) reaction at a silicon center. High diastereoselectivities can be obtained in this efficient unimolecular chain transfer reaction. Less suitable are radicals such as 1 in which an R3 Si group replaces the SnMe3 group. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Radical reactions; Silicon; Silyl ethers; Tin
Year: 1998 PMID： 29711162 DOI： 10.1002/(SICI)1521-3773(19980302)37:4<462::AID-ANIE462>3.0.CO;2-M
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336