| Literature DB >> 29711154 |
Manfred T Reetz1, Gunther Lohmer1, Renate Schwickardi1.
Abstract
A simple solution to the age-old problem of the Heck reaction of cheap but unreactive chloro- and bromoarenes [for example, reaction (1)] has been found in the catalyst [Pd(CH3 CN)2 Cl2 ]⋅6 Ph4 PCl in the presence of N,N-dimethylglycine as additive. The reaction then proceeds with exceptionally high efficiency. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: C-C coupling; Heck reaction; Homogeneous catalysis; Palladium; Regioselectivity
Year: 1998 PMID： 29711154 DOI： 10.1002/(SICI)1521-3773(19980302)37:4<481::AID-ANIE481>3.0.CO;2-I
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336