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Literature DB >> 29711097

Determination of End-to-End Distances in a Series of TEMPO Diradicals of up to 2.8 nm Length with a New Four-Pulse Double Electron Electron Resonance Experiment.

Rainer E Martin¹, Matthias Pannier², François Diederich¹, Volker Gramlich³, Michael Hubrich², Hans W Spiess².

Abstract

A four-pulse version of the pulsed double electron electron resonance (DEER) experiment has been applied to a series of TEMPO diradicals with well-defined interradical distances ranging from 1.4 to 2.8 nm (see picture). The new pulse sequence allows broad distributions of electron-electron distances to be measured without dead-time artifacts. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Keywords: Diradicals; Double electron electron resonance spectroscopy; EPR spectroscopy

Year: 1998 PMID： 29711097 DOI： 10.1002/(SICI)1521-3773(19981102)37:20<2833::AID-ANIE2833>3.0.CO;2-7

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Determination of End-to-End Distances in a Series of TEMPO Diradicals of up to 2.8 nm Length with a New Four-Pulse Double Electron Electron Resonance Experiment.

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