| Literature DB >> 29711084 |
Miwako Mori1, Katsutoshi Hori1, Masaya Akashi1, Masanori Hori1, Yoshihiro Sato1, Mayumi Nishida1.
Abstract
Dry air is the source of molecular nitrogen for reactions with TiL4 , Li, and TMSCl (L = Cl, OiPr; TMS = trimethylsilyl). The nitrogen-titanium complexes thus prepared can be used to synthesize indoles, pyrroles, and lactams from carbonyl compounds. Applying this method to 1 provides access to 2, the key compound in the synthesis of (±)-lycopodine. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Heterocycles; Lycopodine; Nitrogen fixation; Titanium
Year: 1998 PMID： 29711084 DOI： 10.1002/(SICI)1521-3773(19980316)37:5<636::AID-ANIE636>3.0.CO;2-X
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336