| Literature DB >> 29711068 |
Joël Jacob1, Katrin Geßler1, Daniel Hoffmann2, Haruyo Sanbe3, Kyoko Koizumi3, Steven M Smith4, Takeshi Takaha5, Wolfram Saenger1.
Abstract
The cavity of the larger molecule has less space for guests! Unlike the structure of the smaller annular cyclodextrins, that of the higher homologues of cycloamyloses (CAs) with more than ten glucose units contains a 90° kink between adjacent glucose residues within one half of the molecule and a 180° band flip between adjacent units in different halves (see depicted section of the CA14 structure) to yield butterfly-shaped structures with narrow, groovelike cavities. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Conformation analysis; Cyclodextrins; Structure elucidation
Year: 1998 PMID： 29711068 DOI： 10.1002/(SICI)1521-3773(19980316)37:5<605::AID-ANIE605>3.0.CO;2-C
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336