| Literature DB >> 29711060 |
Anthony J Lupinetti1, Gernot Frenking2, Steven H Strauss1.
Abstract
MP2 calculations show that the D∞h isoelectronic dicarbonyl complexes [M(CO)2 ]n (Mn =Rh- , Pd0 , Cu+ , Ag+ , Au+ , Zn2+ , Cd2+ , Hg2+ ) depicted in structure 1 can be classified as classical or nonclassical depending on whether the metal-carbon bond lengths decrease or increase when weak, anionic ligands approach the metal centers. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Ab initio calculations.; Carbonyl complexes; Pi interactions; Transition metals
Year: 1998 PMID： 29711060 DOI： 10.1002/(SICI)1521-3773(19980817)37:15<2113::AID-ANIE2113>3.0.CO;2-2
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336