Literature DB >> 29711033

Novel Distorted Pentagonal-Pyramidal Coordination of Anionic Oxodiperoxo Molybdenum and Tungsten Complexes.

Jean-Yves Piquemal1, Sabine Halut2, Jean-Marie Brégeault1.   

Abstract

Model compounds for silica surfaces modified with metal complexes are provided by the mononuclear anionic diperoxo species 1 and the dinuclear complex anions 2 (M = Mo, W). They were obtained in fair to nearly quantitative yields by the reactions of Ph3 SiOH and [Ph2 Si(OH)]2 O, respectively, with an aqueous solution of [MO(O2 )2 (H2 O)2 ]. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Molybdenum; Peroxo complexes; Si ligands; Tungsten

Year:  1998        PMID: 29711033     DOI: 10.1002/(SICI)1521-3773(19980504)37:8<1146::AID-ANIE1146>3.0.CO;2-X

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  Oxygen transfer in electrophilic epoxidation probed by 17O NMR: differentiating between oxidants and role of spectator metal oxo.

Authors:  Christian Ehinger; Christopher P Gordon; Christophe Copéret
Journal:  Chem Sci       Date:  2018-12-03       Impact factor: 9.825

  1 in total

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