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Literature DB >> 29711025

Topochemical Conversion of a Hydrogen-Bonded Three-Dimensional Network into a Covalently Bonded Framework.

John D Ranford¹, Jagadese J Vittal¹, Daqing Wu¹.

Abstract

Thermal dehydration promotes the topochemical conversion of the hydrogen-bonded dimeric complex [{Zn(sala)(H2 O)2 }2 ]⋅2 H2 O (H2 (sala)=N-(2-hydroxybenzyl)-L-alanine) to generate covalent [{Zn(sala)}n ]. X-ray crystallography reveals that hydrogen bonding plays a key role in this process (see the partial structure on the right). © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities: Chemical Disease

Keywords: Coordination polymers; Crystal engineering; Supramolecular chemistry; Topochemistry; Zinc

Year: 1998 PMID： 29711025 DOI： 10.1002/(SICI)1521-3773(19980504)37:8<1114::AID-ANIE1114>3.0.CO;2-E

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

2 in total

1. Crystal structure of bis-[(S)-2-(2-hy-droxy-benzyl-amino)-4-methyl-penta-noato-κ² N,O ¹](1,10-phenanthroline-κ² N,N')cadmium dihydrate.

Authors: Md Serajul Haque Faizi; Necmi Dege; James Pogrebetsky; Turganbay S Iskenderov
Journal: Acta Crystallogr E Crystallogr Commun Date: 2018-10-12

2. Structural characterization and DFT study of bis-{(S)-2-[(2-hy-droxy-benz-yl)amino]-3-(4-hy-droxy-phen-yl)propano-ato-κ²N,O}(1,10-phenanthroline-κ²N,N')cadmium(II) tetra-hydrate.

Authors: Md Serajul Haque Faizi; Necmi Dege; James Pogrebetsky; Turganbay S Iskenderov
Journal: Acta Crystallogr E Crystallogr Commun Date: 2018-08-24

2 in total

Topochemical Conversion of a Hydrogen-Bonded Three-Dimensional Network into a Covalently Bonded Framework.

1. Crystal structure of bis-[(S)-2-(2-hy-droxy-benzyl-amino)-4-methyl-penta-noato-κ2 N,O 1](1,10-phenanthroline-κ2 N,N')cadmium dihydrate.

2. Structural characterization and DFT study of bis-{(S)-2-[(2-hy-droxy-benz-yl)amino]-3-(4-hy-droxy-phen-yl)propano-ato-κ2N,O}(1,10-phenanthroline-κ2N,N')cadmium(II) tetra-hydrate.

1. Crystal structure of bis-[(S)-2-(2-hy-droxy-benzyl-amino)-4-methyl-penta-noato-κ² N,O ¹](1,10-phenanthroline-κ² N,N')cadmium dihydrate.

2. Structural characterization and DFT study of bis-{(S)-2-[(2-hy-droxy-benz-yl)amino]-3-(4-hy-droxy-phen-yl)propano-ato-κ²N,O}(1,10-phenanthroline-κ²N,N')cadmium(II) tetra-hydrate.