Literature DB >> 29710941

The First Structural Characterization of an Azoaromatic Radical Anion Stabilized by Dicopper(I) Coordination.

Nataša Doslik1, Torsten Sixt1, Wolfgang Kaim1.   

Abstract

Double chelate coordination of [Cu(Ph3 P)2 ]+ stabilizes the radical anion of 2,2'-azobis(5-chloropyrimidine), which exhibits a N-N bond length of 1.345(7) Å in the complex (see picture). This is consistent with a one-electron reduced azo functionality. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Azo compounds; Bond order; Copper; EPR spectroscopy; Radical ions

Year:  1998        PMID： 29710941     DOI： 10.1002/(SICI)1521-3773(19980918)37:17<2403::AID-ANIE2403>3.0.CO;2-J

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Synthesis of Pyridylimido Complexes of Tantalum and Niobium by Reductive Cleavage of the N═N Bond of 2,2'-Azopyridine: Precursors for Early-Late Heterobimetallic Complexes.

Authors:  Kento Kawakita; Yuya Kakiuchi; Evan P Beaumier; Ian A Tonks; Hayato Tsurugi; Kazushi Mashima
Journal:  Inorg Chem       Date:  2019-09-25       Impact factor: 5.165

2.  A supramolecular radical cation: folding-enhanced electrostatic effect for promoting radical-mediated oxidation.

Authors:  Bohan Tang; Wan-Lu Li; Yang Jiao; Jun-Bo Lu; Jiang-Fei Xu; Zhiqiang Wang; Jun Li; Xi Zhang
Journal:  Chem Sci       Date:  2018-05-16       Impact factor: 9.825

3.  Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands.

Authors:  Jarl Ivar van der Vlugt
Journal:  Chemistry       Date:  2018-11-26       Impact factor: 5.236
  3 in total

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