| Literature DB >> 29710928 |
Oliver Hochrein1, Yuri Grin2, Rüdiger Kniep1.
Abstract
Unbridged Mn2 units are present in the hexanitridodimanganate(IV) ions of the title compound. This is the first example of a Mn-Mn single bond within a complex anion in which the manganese centers have the high oxidation state +4. According to ELF calculations, the Mn-Mn bond can be regarded as a two-electron, two-center bond. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Electron localization function; Electronic structure; Manganese; Nitrides
Year: 1998 PMID： 29710928 DOI： 10.1002/(SICI)1521-3773(19980619)37:11<1582::AID-ANIE1582>3.0.CO;2-D
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336