| Literature DB >> 29710922 |
Maurice J van Eis1, Corine M D Komen1, Franciscus J J de Kanter1, Willem H de Wolf1, Koop Lammertsma1, Friedrich Bickelhaupt1, Martin Lutz2, Anthony L Spek2.
Abstract
Three novel aspects emerge for the reaction of [5]metacyclophane (1) with the (intermediate) phenylphosphinidene complex 2 to give the 7-phosphanorbornadiene 3. It is the first 1,4-addition of a phosphinidene complex to an unsaturated system, the first addition of a phosphinidene complex to a benzene ring, and the first [4+1] cycloaddition to an aromatic compound. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Cycloadditions; Cyclophanes; Density functional calculations; Phosphinidene complexes; Phosphorus
Year: 1998 PMID： 29710922 DOI： 10.1002/(SICI)1521-3773(19980619)37:11<1547::AID-ANIE1547>3.0.CO;2-S
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336