| Literature DB >> 29710916 |
Daniele Hoffmann1, Thomas Kottke2, Richard J Lagow3, Ruthanne D Thomas4.
Abstract
Extraordinary solubility in hydrocarbons is exhibited by the novel superaggregate Li33 H17 (OtBu)16 , which crystallizes from photolyzed solutions of lithium tert-butoxide and tert-butyllithium (ROLi:RLi≥7:3). The structure of the compound (the framework of Li, H, and O atoms without tBu groups is shown on the right) resembles a disrupted lithium hydride lattice with an inner hydride-rich core and an outer shell of lipophilic tert-butoxide groups. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Hydrides; Lithium; Structure elucidation
Year: 1998 PMID： 29710916 DOI： 10.1002/(SICI)1521-3773(19980619)37:11<1537::AID-ANIE1537>3.0.CO;2-U
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336