| Literature DB >> 29648556 |
Javier Ruiz1, Daniel Sol, María A Mateo, Marilín Vivanco.
Abstract
The isocyanide ligands in complexes fac-[Mn(CNR)(bipy)(CO)3]+ are selectively transformed into formamidines, carbodiimides and formimidates upon nucleophilic addition of NH2Me or alkoxides and subsequent treatment with Ag2O, which promotes tautomerization or oxidation processes of the former carbene ligands.Entities:
Year: 2018 PMID： 29648556 DOI： 10.1039/c8dt01200h
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390